Normal telepathy seems to work through mechanical waves (vibration on the air). That way it works like a telephone were the sound is transmitted through invisible wires in the air.
Misaki's power seems to work through electromagnetic waves that she use to affect others brains. Misaki's "telepathy" is more like writing on the person brain the information she wants to tell them. And as electromagnetic waves, it can be blocked by Misaka's barrier.
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